名古屋大学大学院理学研究科／名古屋大学物質科学国際研究センター 分子機能化学研究室 発表論文 2015

論文発表 Original Papers 2024

• Chiral Honeycomb Lattices of Nonplanar π-Conjugated Supramolecules with Protected Dirac and Flat Bands
  • Nemoto Ryohei, Arafune Ryuichi, Nakano Saya, Tsuchiizu Masahisa, Takagi Noriaki, Suizu Rie, Uchihashi Takashi, Awaga Kunio
    ACS NANO (8. July 2024) (DOI:10.1021/acsnano.4c04496)

論文発表 Original Papers 2023

• Synthesis of a novel triptycene-derived protected dithiolene ligand precursor for tri-nuclear mixed ligand metal dithiolene complexes
  • Wang Ali, Shuku Yoshiaki, Suizu Rie, Robertson Neil,Awaga Kun
    Chemistry Letters Vol: 53 issue:2 (10. February 2024) (DOI:10.1093/chemle/upad051)
• Critical Transition to a Highly Conductive State through PEDOT Oligomer Percolation in Redox-Active COFs
  • Chaoqun Cao, Qi Chen, Rie Suizu and Kunio Awaga
    Journal of Materials Chemistry C (6. February 2024) (DOI:https://doi.org/10.1039/D3TC04794F)
• X-ray crystallographic analysis of the antiferromagnetic low-temperature phase of galvinoxyl: investigating magnetic duality in organic radicals
  • Rie Suizu, Yoshiaki Shuku, Vincent Robert, Pablo Roseiro, Nadia Ben Amor, Zain Khawar, Neil Robertson and Kunio Awaga,
    DALTON TRANSACTIONS,53, 1961-1965 (13.December 2023) (DOI:https://doi.org/10.1039/D3DT03601D)
• Optoelectronic conversion and polarization hysteresis in organic MISM and MISIM devices with DA-type single-component molecules
  • Akihiro Tomimatsu, Rie Suizu, Miyabi Nakazawa,Takashi Shirahata, Yohji Misaki, Naoya Kinoshita and Kunio Awaga,
    FARADAY DISCUSSIONS (4.September 2023) (DOI:https://DOI10.1039/d3fd00125c)
• Ideal trigonal prismatic coordination geometry of Co(II) in a honeycomb MOF with a triptycene-based ligand
  • Y. Shuku, R. Suizu, M. Tsuchiizu, K. Awaga,
    Chem. Commun. 59, 10105-10108.(27.July 2023) (DOI:https://doi.org/10.1039/D3CC02986G)
• Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
  • Qi Chen, Zhongyue Zhang, Kunio Awaga,
    JOVE-JOURNAL OF VISUALIZED EXPERIMENTS, 196, (9.June.2023)(DOI:10.3791/65335-v)
• Engineering Dirac cones and topological flat bands with organic molecules
  • Y. Shuku, R. Suizu, S. Nakano, M. Tsuchiizu, K. Awaga,
    (2023) Phys. Rev. B, 107, 15.(12. April 2023) (DOI: https://doi.org/10.1103/ PhysRevB.107.155123)

論文発表 Original Papers 2022

• Enhanced Circularly Polarized Luminescence by a Homochiral Guest–Host Interaction in Gyroidal MOFs, [Ru(bpy)3] [M2(ox)3] (bpy = 2,2′-Bipyridyl, ox = Oxalate, M = Zn, Mn)
  • Kazuya Nakashima , Rie Suizu, Shuhei Morishita, Noriaki Tsurumachi, Masahiro Funahashi, Hyuma Masu, Ryuki Ozawa, Kazuki Nakamura, and Kunio Awaga
    ACS Materials Au, March 17 2023 DOI:10.1021/acsmaterialsau.2c00081
• Isomeric Triptycene Triquinones as Universal Cathode Materials for High Energy Alkali Metal Batteries
  • Hyunji Park, Yoshiaki Shuku, Jihyun Lee, Kyunam Lee, Dong Joo Min, Byeong-Kwan An, Kuino Awaga, Soo Young Park, Ji Eon Kwon,
    Butteries& Supercaps, Volume6, Issue3 (March 2023) DOI:10.1002/batt.202200497
• Fabrication of MXene transparent conductive films via transfer process
  • Yuki Shibata, Rie Suizu, Kunio Awaga, Jun Hirotani, Haruka Omachi ,
    Applied Physics Express, 16 (3) (9.March 2023) DOI: 10.35848/1882-0786/acbbb8
• Graphite-like Charge Storage Mechanism in a 2D pi-d Conjugated Metal-Organic Framework Revealed by Stepwise Magnetic Monitoring
  • Q. Chen, O. Adeniran, ZF. Liu, ZY. Zhang, K. Awaga,
    J Am Chem Soc, 145(2)1062-1071(9. Jan.2023) DOI: 10.1021/jacs.2c10650
• Synthesis of Isomeric Tb3+-Phthalocyanine Double-Decker Complexes Depending on the Difference in the Direction of Coordination Plane and Their Magnetic Properties
  • Y. Yamada, H. Nakajima, C. Kobayashi, Y. Shuku, K. Awaga, S. Akine, K. Tanaka,
    Chem Eur J,(Volume 29, issue1 2.January 2023) DOI: 10.1002/chem.202203272
• CNT Gels Formed by a Triptycene Analogue Enabling Coexistence of CNT-gelator and Intergelator Interactions
  • R. Ushiroguchi, R. Suizu, Y. Matsunaga, H. Omachi, Y. Doi, Y. Masubuchi, S. Bandow, K. Awaga,
    Chem Lett, Volume 51 No.111070-1073(2022) DOI: 10.1246/cl.220319
• Improvement in Cycle Life of Organic Lithium-Ion Batteries by In-Cell Polymerization of Tetrathiafulvalene-Based Electrode Materials
  • A. Yoshimura, K. Hemmi, H. Moriwaki, R. Sakakibara, H. Kimura, Y. Aso, N. Kinoshita, R. Suizu, T. Shirahata, MSR. Yao, H. Yorimitsu, K. Awaga, Y. Misaki,
    ACS Appl Mater Interfaces, 14(31)35978-35984(2022)
• N-doped nonalternant aromatic belt via a six-fold annulative double N-arylation
  • H. Sato, R. Suizu, T. Kato, A. Yagi, Y. Segawa, K. Awaga, K. Itami,
    Chem Sci, Volume13(34)9947-9951(2022)
• Duty-cycle dependence of photo-induced displacement current in MISIM photocells
  • Akihiro Tomimatsu, Seiya Yokokura , Kunio Awaga
    Organic Electronics Volume 109, ( 2022), 106632 DOI: 10.1016/j.orgel.2022.106632
• Salt-Assisted Pyrolysis of Covalent Organic Framework for Controlled Active Nitrogen Functionalities for Oxygen Reduction Reaction
  • Youn Charles-Blin ,Taiga Kondo ,Yang Wu ,Shunji Bandow , Kunio Awaga
    BCSJ, 2022, Volume:95, No.6 DOI: 10.1246/bcsj.20220094

論文発表 Original Papers 2021

• Exfoliation of Al-residual multilayer MXene using tetramethylammonium bases for conductive film applications
  • Saita, E., Iwata M., Shibata Y., Matsunaga Y., Suizu R., Awaga K., Hirotani J., Omachi H.
    Front. Chem., 2022, 10, 841313. DOI: 10.3389/fchem.2022.841313
• Line graph theory reveals hidden spin frustrationand bond frustration in molecular crystals withstrong isotropy
  • Rie Suizu and Kunio Awaga
    Journal of Materials Chemistry C, Volume:10 Issue:22 , Pages:1196-1203 , Published: 7th Dec 2021, (DOI: 10.1039/d1tc05161j)
• 3D supramolecular chiral crystal structures of radical anion salts of (−)-NDI-Δ and possible magnetic phase diagrams
  • Asato Mizuno, Yoshiaki Shuku, Rie Suizu, Masahisa Tsuchiizu and Kunio Awaga
    CrystEngComm, Volume:29 Issue:23 , Pages:5053-5059 , Published: 7th Jun 2021, (https://doi.org/10.1039/D1CE00628B )
• Stabilization of Interfacial Polarization and Induction of Polarization Hysteresis in Organic MISIM Devices.
  • Yokokura S., Tomimatsu A., Ishiguro J., Harada J., Takahashi H., Takahashi Y., Nakamura Y., Kishida H., Suizu R., Matsushita M.M., Awaga K.
    ACS Applied Materials & Interfaces, Volume:13 Issue:27 , Pages:31928-31933 , Published:1st July 2021, (DOI: 10.1021/acsami.1c08417 )
• Evaluating the high-pressure structural response and crystal lattice interactions of the magnetically-bistable organic radical TTTA
  • Jonathan G. Richardson, Asato Mizuno, Yoshiaki Shuku, Kunio Awaga, Neil Robertson, Carole A. Morrison, Mark R. Warren, David R. Allan, Stephen A. Moggach
    CrystEngComm, Volume:23 Issue:25 , Pages:4444-4450 , Published: 19 May 2021, (DOI:10.1039/d1ce00577d)

論文発表 Original Papers 2020

• Electrochemical Tuning-Induced Magnetic Transitions in Geometrically Frustrated Spinel LixMn2O4 (0.07 ≤ x ≤ 0.93)
  • Qi Chen, Zhongyue Zhang, and Kunio Awaga
    The Journal of Physical Chemistry C, Volume: 125 Issue: 14 , Pages: 7663-7771 , Published: 12 March 2021, (https://doi.org/10.1021/acs.jpcc.1c00291)
• Enhanced proton conductivity in a flexible metal-organic framework promoted by single-crystal-to-single-crystal transformation
  • X. Chen, Z. Zhang, J. Chen, S. Sapchenko, X. Han, I. Da-Silva, M. Li, I. Vitorica-Yrezabal, G. Whitehead, C.C. Tang, K. Awaga, S. Yang, M. Schroder,
    Chem. Commun, 2021 Issue: 1 , Pages:7593-7597 , Published: 17 November 2020, (https://doi.org/10.1039/D0CC05270A)
• Variable Host–Guest Charge-Transfer Interactions in 1D Channels Formed in a Molecule-Based Honeycomb Lattice of Phenazine Analogue of Triptycene
  • Ryo Ushiroguchi, Yoshiaki Shuku, Rie Suizu, and Kunio Awaga
    Crystal Growth & Design, Volume:20 Issue: 12 , Pages:7593-7597 , Published: 28 September 2020, (https://doi.org/10.1021/acs.cgd.0c01176)
• Quantum Spin Liquid State in a Two-Dimensional Semiconductive Metal–Organic Framework
  • Yuki Misumi,Akira Yamaguch, Zhongyue Zhang, Taku Matsushita, Nobuo Wada, Masahisa Tsuchiizu, and Kunio Awaga
    J. Am. Chem. Soc., Volume:142 Issue: 39, Pages:16513-16547, Published: 4 July 2020, (https://doi.org/10.1021/jacs.0c05472)
• Effect of fluorination on the crystal and electronic structure of organometallic cyclopentadienyl-phenylenediamino-cobalt complexes
  • Luca Pilia, Yoshiaki Shuku, Simon Dalgleish, Detlef W.M. Hofmann, Nicola Melis, Kunio Awaga and Neil Robertson
    Journal of Organometallic Chemistry , Volume: 918, Pages: 121277, Published: 1 July 2020, (DOI: 10.1016/j.jorganchem.2020.121277)
• Electric and Thermosalient Properties of a Charge-Transfer Complex Exhibiting a Minor Valence Instability Transition
  • Yukihiro Takahash, Tsubasa Kondo, Seiya Yokokura, Mika Takehisa, Jun Harada, Tamotsu Inabe, Michio M. Matsushita, and Kunio Awaga
    Crystal Growth & Design, Volume: 20, Pages: 4758–4763, Published: 21 May 2020, (DOI: 10.1021/acs.cgd.0c00516)
• Chemical potentials of electric double layers at metal–electrolyte interfaces: dependence on electrolyte concentration and electrode materials, and application to field-effect transistors
  • Chihiro Nanjo, Daisuke Yokogawa, Michio M. Matsushitaa and Kunio Awaga
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS , Volume: 22, Pages: 12395-12402, Published: 14 April 2020, (DOI: 10.1039/d0cp00423e)

発表論文 Original Papers 2019

• STRUCTURAL, ELECTRONIC, AND MAGNETIC PROPERTIES OF COBALT TETRAKIS(THIADIAZOLE) PORPHYRAZINE MOLECULE FILMS ON AU(111)
  • Wang Yu, Hou Jie, Eguchi Keitaro, Nanjo Chihiro, Takaoka Tsuyoshi, Sainoo Yasuyuki, Awaga Kunio, Komeda Tadahiro
    ACS OMEGA ,Volume: 5 Issue: 12, Pages: 6676-6683, Published:31 March 2020, (DOI:10.1021/acsomega.9b04453)
• ENHANCED MAGNETIC SPIN-SPIN INTERACTIONS OBSERVED BETWEEN PORPHYRAZINE DERIVATIVES ON AU(111)
  • Hou Jie, Wang Yu, Eguchi Keitaro, Nanjo Chihiro, Takaoka Tsuyoshi, Sainoo Yasuyuki, Arafune Ryuichi, Awaga Kunio, Komeda Tadahiro
    COMMUNICATIONS CHEMISTRY ,Volume: 3 Issue: 1, Article number: 36, Published:20 March 2020, (DOI:10.1038/s42004-020-0282-5)
• Potential modulations in flatland: near-infrared sensitization of MoS2 phototransistors by a solvatochromic dye directly tethered to sulfur vacancies
  • Simon Dalgleish, Louisa Reissig, Yoshiaki Shuku, Giovanni Ligorio, Kunio Awaga, Emil J. W. List-Kratochvil
    Scientific Reports ,Volume: 9, Article number: 16682 , Published:13 November 2019(DOI:10.1038/s41598-019-53186-2)
• Salt-assisted pyrolysis of covalent organic frameworks to porous heteroatom-doped carbons for supercapacitive energy storage
  • Dongwan Yan, Yang Wu, Ryo Kitaura, Awaga Kunio
    Journal of Materials Chemistry A ,Volume: 7, Number: 47, Pages: 26645-27188, Published:Sep. 26 2019(DOI: 10.1039/C9TA05150C)
• High Ambipolar Mobility in a Neutral Radical Gold Dithiolene Complex
  • Mizuno Asato, Benjamin Helen, Shimizu Yasuhiro, Shuku Yoshiaki, Matsushita Michio M., Robertson Neil, Awaga Kunio
    ADVANCED FUNCTIONAL MATERIALS , Volume: 29 Issue: 42, Article Number: 1904181 , Published:Aug. 12 2019(DOI: 10.1002/adfm.201904181)
• In situ formed [M(CN)(9)] (M = W, Mo) as a building block for the construction of two nona-cyanometalate-bridged heterometallic coordination polymers
  • Qian Jun, Yoshikawa Hirofum, Humphrey Mark G., Zhang Jinfang, Awaga Kunio, Zhang Chi
    View Web of Science ResearcherID and ORCID CRYSTENGCOMM , Volume: 21 Issue: 29 Pages: 4363-4372 , Published:AUG 7 2019(DOI: 10.1039/c9ce00579j)
• Rate-determining process in MISIM photocells for optoelectronic conversion using photo-induced pure polarization current without carrier transfer across interfaces
  • Tomimatsu Akihiro, Yokokura Seiya, Reissig Louisa, Dalgleish Simon, Matsushita Michio M., Awaga Kunio
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS , Volume: 21 Issue: 25 Pages: 13440-13445, Published:JUL 7 2019(DOI: 10.1039/c9cp01221d)
• Exploration of Li-Organic Batteries Using Hexaphyrin as an Active Cathode Material
  • Shin Ji-Young, Zhang Zhongyue, Awaga Kunio, Shinokubo Hiroshi
    MOLECULES Volume: 24 Issue: 13 Article Number: 2433, Published: JUL 1 2019(DOI: 10.3390/molecules24132433)
• Auxiliary ligand-induced structural diversities of octacyanometalate-based heterobimetallic coordination polymers towards diverse magnetic properties
  • Qian Jun, Yoshikawa Hirofumi, Hu Jingchun, Humphrey Mark G., Zhang Jinfang, Awaga Kunio, Zhang C
    View Web of Science ResearcherID and ORCID DALTON TRANSACTIONS ,Volume: 48 Issue: 22 Pages: 7666-7676, Published:JUN 14 2019(DOI: 10.1039/c9dt00654k)
• Ionic liquid thin layer-induced memory effects in organic field-effect transistors
  • Eguchi K, Matsushita M.M., Awaga K.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS , Volume: 21 Issue: 35 Pages: 18823-18829 , Published:May 31 2019(DOI:10.1039/C9CP01647C)

発表論文 Original Papers 2018

• Electron Highways into Nanochannels of Covalent Organic Frameworks for High Electrical Conductivity and Energy Storage
  • Wu, Yang, Yan, Yan, Dongwan, ,Zhang, Zhongyue, M.M. Matsushita, K.Awaga
    ACS APPLIED MATERIALS & INTERFACES , FEB. 27 2019,11(8), 7661-7665 (DOI: 10.1021/acsami.8b21696 )
• Recent Developments in Molecular Spin Gyroid Research
  • Mizuno A., Shuku Y., Awaga K.
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN , Volume: 92 Issue: 6 Pages: 1068-1093 , Published:FEB. 26 2019(DOI: 10.1246/bcsj.20190033)
• In Situ Real-Time Measurements for Ambipolar Channel Formation Processes in Organic Double-Layer Field-Effect Transistors of CuPc and F16CuPc
  • K. Eguch, M. M. Matsushita, K. Awaga
    J. Phys. Chem. C, 2018, 122(45), 26054-26060(DOI:10.1021/acs.jpcc.8b08744)
• Towards high-bandwidth organic photodetection based on pure active layer polarization
  • L. Reissig, S. Dalgleish, K. Awaga
    Scientific Reports, 2018, 8, 15415(DOI:10.1038/s41598-018-33822-z)
• 3D molecular network and magnetic ordering, formed by multi-dentate magnetic couplers, bis(benzene)chromium(I) and [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazolidyl
  • Y. Shuku, Y. Hirai, N. A. Semenov, E. Kadilenko, N. P. Gritsan, A. V. Zibarev, O. A. Rakitin and K. Awaga
    Dalton Trans., 2018,47, 9897-9902 (DOI:10.1039/C8DT02214C)
• Structural and Electronic Effects Due to Fluorine Atoms on Dibenzotetraaza-Annulenes Complexes
  • L. Pilia, Y. Shuku, S. Dalgleish, K. Awaga, N. Robertson
    ACS Omega, 2018, 3(8), 10074-10083 (DOI:10.1021/acsomega.8b01442)
• Multifunctional Dithiadiazolyl Radicals: Fluorescence, Electroluminescence, and Photoconducting Behavior in Pyren-1 '-yl-dithiadiazolyl
  • Y. Beldjoudi, M. A. Nascimento, Y. J. Cho, H. Yu, H. Aziz, D. Tonouchi, K. Eguchi, M. M. Matsushita, K. Awaga, I.Osorio-Roman, C. P. Constantinides, J. M. Rawson
    J. Am. Chem. Soc., 2018, 140(20), 6260-6270 (DOI:10.1021/jacs.7b12592)
• Inter-molecule interaction for magnetic property of vanadyl tetrakis (thiadiazole) porphyrazine film on Au(111)
  • J. Hou,Y. Wang, K. Eguchi, C. Nanjo, T. Takaoka, Y. Sainoo, K. Awaga, T. Komeda,
    Appl. Sur. Sci., 2018, 440, 16-19(DOI:10.1016/j.apsusc.2018.01.001)
• An exotic band structure of a supramolecular honeycomb lattice formed by a pancake π–π interaction between triradical trianions of triptycene tribenzoquinone
  • Y. Shuku, A. Mizuno, R. Ushiroguchi, C. S. Hyun, Y.J. Ryu, B.K. An, J.E. Kwon, S.Y. Park, M. Tsuchiizu, K. Awaga
    Chem. Comm., 2018, 54, 3815 - 3818 (DOI: 10.1039/C8CC00753E)
• Influence of Air Exposure on Photocarrier Generation in Amorphous and Phase II Thin Films of Titanyl Phthalocyanine
  • K. Eguchi, Y. Imai, M. M. Matsushita, K. Awaga
    J. Phys. Chem. C, 2018, 122(14), 7731-7736(DOI:10.1021/acs.jpcc.8b00290)
• Nanopore-induced Host-guest Charge Transfer Phenomena in a Metal-Organic Framework
  • S. Yamamoto, J. Pirillo, Y. Hijikata, Z. Zhang and K. Awaga
    Chem. Sci., 2018, 9, 3282 – 3289(DOI:10.1039/C7SC05390H)

発表論文 Original Papers 2017

• Controlling the crystallinity and crystalline orientation of "shuttlecock" naphthalocyanine films for near-infrared optoelectronic applications
  • S. Dalgleish, L. Reissig, Y. Shuku, C. Gourlaouen, S. Vela, K. Awaga
    J. Mater. Chem. C, 2018, 6, 1959-1970(DOI: 10.1039/c7tc05521h)
• Giant negative magnetoresistance in Ni(quinoline-8-selenoate) (2)
  • N. Black, D. Tonouchi, M. M. Matsushita, J.D. Woollins, K. Awaga, N. Robertson
    Phys. Chem. Chem. Phys., 2018, 20(1), 514-519(DOI:10.1039/c7cp06273g)
• A Novel Strategy to Functionalize Covalent Organic Frameworks for High-Energy Rechargeable Lithium Organic Batteries via Graft Polymerization in Nano-Channels
  • Y. Wu, Z. Zhang, S. Bandow, K. Awaga
    Bull. Chem. Soc. Japan, 2017, 90(12), 1382-1387(DOI:10.1246/bcsj.20170247)
• 3D Spin-Liquid State in an Organic Hyperkagome Lattice of Mott Dimers
  • A. Mizuno, Y. Shuku, M. M. Matsushita, M. Tsuchiizu, Y. Hara, N. Wada, Y. Shimizu, K. Awaga
    Phys. Rev. Lett., 2017, 119(5), 057201(DOI:10.1103/PhysRevLett.119.057201)
• Negative differential resistance in the Peierls insulating phases of TTF-TCNQ
  • D. Tonouchi, M. M. Matsushita, K. Awaga
    Phys. Rev. B., 2017, 96(4), 045116(DOI:10.1103/PhysRevB.96.045116)
• Fluorination induced electronic effects on a Pt(II) square-planar complex of the o-phenylenediimine ligand
  • L. Pilia, M. M. Matsushita, K. Awaga, N. Robertson
    New J. Chem., 2017, 41(13), 5487-5492(DOI:10.1039/C7NJ00394C)
• Templating effects of tetrakis(thiadiazole) porphyrazine on the structure and optical properties of copper phthalocyanine thin films
  • K. Eguchi, S. Heutz, K. Awaga
    J. Porphyrins Phthalocyanines, 2017, 21(4-6), 322-326(DOI:10.1142/S1088424617500171)

発表論文 Original Papers 2016

• Molecular and thin film properties of cobalt half-sandwich compounds for optoelectronic application
  • M. Reinhard, S. Dalgleish, Y. Shuku, L. Reissig, M. M. Matsushita, J. Crain, K. Awaga, N. Robertson
    Phys. Chem. Chem. Phys., 2017, 19(9), 6768-6776(DOI: 10.1039/c6cp08685c)
• Redox-active metal-organic frameworks as electrode materials for batteries
  • Z. Zhang, K. Awaga
    MRS Bulletin, 2016, 41, 883-889(DOI: 10.1557/mrs.2016.245)
• Transport Characteristics of the Organic Field-Effect Transistors Based on Charge Transfer Complex as Semiconductors
  • S. Yokokura, Y. Takahashi, H. Hasegawa, J. Harada, T. Inabe, M. M. Matsushita, K. Awaga
    J. Nanosci. Nanotech., 2016, 16, 3355-3359(DOI: 10.1166/jnn.2016.12301)
• Integration of Paramagnetic Diruthenium Complexes into an Extended Chain by Heterometallic Metal-Metal Bonds with Diplatinum Complexes
  • K. Uemura, N. Uesugi, A. Matsuyama, M. Ebihara, H. Yoshikawa, K. Awaga
    Inorg. Chem., 2016, 55, 7003-7011(DOI: 10.1021/acs.inorgchem.6b00741)
• Highly-oriented molecular arrangements and enhanced magnetic interactions in thin films of CoTTDPz using PTCDA templates
  • K.. Eguchi, C. Nanjo, K. Awaga, H. H. Tseng, P. Robaschik and S. Heutz
    Phys. Chem. Chem. Phys., 2016, 18(26), 17360-17365(DOI: 10.1039/C6CP01932C)
• A perovskite based plug and play AC photovoltaic device with ionic liquid induced transient opto-electronic conversion
  • S. Karak, C. Nanjo, M. Odaka, K. Yuyama, G. Masuda, M. M. Matsushita, K. Awaga
    J. Mater. Chem. A, 2016, 4, 9019-9028(DOI: 10.1039/C6TA01427E)

発表論文 Original Papers 2015

• Electrochemical deposition of highly-conducting metal dithiolene films
  • E. Allwright, G. Silber, J. Crain, M.M. Matsushita, K. Awaga, N. Robertson,
    Dalton Trans, 2016, 3, 45, 9363-9368. (DOI: 10.1039/c6dt01166g)
• Discovery of a “Bipolar Charging” Mechanism in the Solid-State Electrochemical Process of a Flexible Metal–Organic Framework
  • Z. Zhang, H. Yoshikawa and K. Awaga
    Chem. Mater.,2016, 28(5), 1298-1303(DOI: 10.1021/acs.chemmater.5b04075)
• Synthesis of Vanadium-Incorporated, Polyoxometalate-Based Open Frameworks and Their Applications for Cathode-Active Material
  • Z. Zhang, H. Yoshikawa, Z. Zhang, T. Murayama, M. Sadakane, Y. Inoue, W. Ueda, K. Awaga and M. .Hara
    Eur. J. Inorg. Chem., 2016, 8, 1242-1250(DOI: 10.1002/ejic.201501396)
• Factors affecting the polarity and magnitude of photoresponse of transient photodetectors
  • L. Reissig, K. Mori, R. Treadwell, S. Dalgleish and K. Awaga
    Phys. Chem. Chem. Phys., 2016, 18, 6821-6830 (DOI: 10.1039/c6cp00093b)
• A differential photodetector: Detecting light modulations using transient　photocurrents
  • L. Reissig, S. Dalgleish and K. Awaga
    AIP Advances, 2016, 6, 015306 (DOI: 10.1063/1.4939921)
• Self-assembled honeycomb lattice in the monolayer of cyclic thiazyl diradical BDTDA (=4,4’-bis(1,2,3,5-dithiadiazolyl)) on Cu(111) with a zero-bias tunneling spectra anomaly
  • M. Yamamoto, R. Suizu, S. Dutta, P. Mishra, T. Nakayama, K. Sakamoto, K. Wakabayashi, T. Uchihashi, and K. Awaga
    Sci. Rep., 2015, 5, 18359 (DOI:10.1038/srep18359)
• On-tip photodetection: a simple and universal platform for optoelectronic screening
  • Dalgleish S., Reissig L., Sudo Y., Awaga K.
    Chemical Communications, 2015 9,Vol.: 51 Issue: 91, 16401-16404 (DOI:10.1039/c5cc06237c)
• Spatially inhomogeneous, stepwise phase transitions in a thiazyl diradical: a structural mismatch induced by lattice transformation
  • R. Suizu, A. Iwasaki, Y. Shuku, and K. Awaga
    J. Mater. Chem. C, 2015, 3, 7968-7977 (DOI: 10.1039/c5tc01410g)
• Discovery of the K4 Structure Formed by a Triangular π Radical Anion
  • A. Mizuno, Y. Shuku, R.Suizu, M. M. Matsushita, M. Tsuchiizu, D. R. Mañeru, F. Illas, V. Robert, and K. Awaga
    J. Am. Chem. Soc., 2015, 137, 7612−7615 (DOI: 10.1021/jacs.5b04180)　
• Factors Affecting the Stability and Performance of Ionic Liquid-Based Planar Transient Photodetectors
  • S. Dalgleish, L. Reissig, L. Hu, M. M. Matsushita, Y. Sudo and K. Awaga
    Langmuir, 2015, 31(18), 5235-5243 (DOI: 10.1021/la504972q)　
• Organic optoelectronic interfaces with anomalous transient photocurrent
  • L. Hu, X. Liu, S. Dalgleish, M. M. Matsushita,H. Yoshikawa and K. Awaga
    J. Mater. Chem. C, 2015, 3, 5122-5135 (DOI:10.1039/c5tc00414d) 　
• Photocurrent Generation in Organic Photodetectors with Tailor-Made Active Layers Fabricated by Layer-by-Layer Deposition
  • B. Vonhoeren, S. Dalgleish, L. Hu, M. M. Matsushita, K. Awaga, B.J. Ravoo
    ACS Applied Materials & Interfaces, 2015, 7(13), 7049-7053 (DOI:10.1021/am509031u)
• External-Template-Assisted Formation of Octacyanometalate-Based M^V-Mn^II (M = W, Mo) Bimetallic Coordination Polymers with Magnetic Properties
  • Q. Jun, Hu. Jingchun, H. Yoshikawa, Z. Jinfang, K. Awaga, Z. Chi
    European Journal of Inorganic Chemistry, 2015, 12, 2110-2119 (DOI:10.1002/ejic.201403223)
• Switching of Transfer Characteristics of an Organic Field-Effect Transistor by Phase Transitions: Sensitive Response to Molecular Dynamics and Charge Fluctuation
  • Yokokura S., Takahashi Y., Nonaka H., Hasegawa H., Harada J., Inabe T., Kumai R., Okamoto H., Matsushita M.M., Awaga K.
    Chemistry of Materials, 2015 5, Vol.: 27 Issue: 12, 4441-4449 (DOI:10.1021/acs.chemmater.5b01383)

発表論文 Original Papers 2014

• A Three-Dimensional Hetero-Bimetallic Coordination Polymer with Unusual (4,5)-Connected Topology and Ferrimagnetic Property Based on Octacyanotungstate and Polydentate Ligand
  • J.Qian, J. Hu, H. Yoshikawa, J. Zhang, K. Awaga, and C. Zhang
    Cryst. Growth Des., 2014, 14(5), 2288-2295 (DOI: 10.1021/cg4019053)
• Theoretical investigation of molecular and electronic structure changes of the molecular magnet Mn12 cluster upon super-reduction
  • Y. Nishimoto, H. Yoshikawa, K. Awaga, M. Lundberg, and S. Irle
    Physica Status Solidi (RRL) - Rapid Research Letters, 2014, 8(6), 517-521 (Selected as a back cover picture) (DOI: 10.1002/pssr.201409094)
• Cathode Composition Dependence of the Battery Performance of Polyoxometalate (POM)-Molecular Cluster Batteries
  • H. Wang, T. Yamada, S. Hamanaka, H. Yoshikawa, and K. Awaga
    Chem. Lett, 2014, 43, 1067-1069 (Virtual Issue on "Coordination Programming") (DOI: 10.1246/cl.140233)
• The solid-state electrochemical reduction process of magnetite in Li batteries: in-situ magnetic measurements toward electrochemical magnets
  • T. Yamada, K. Morita, K. Kume, H. Yoshikawa, and K. Awaga
    J. Mater. Chem. C, 2014, 2(26), 5183-5188 (DOI: 10.1039/C4TC00299G)
• Super-reduced polyoxometalates: Excellent molecular cluster battery components and semipermeable molecular capacitors
  • Y. Nishimoto, D. Yokogawa, H. Yoshikawa, K. Awaga, S. Irle
    J. Am. Chem. Soc., 2014, 136(25), 9042-9052 (DOI: 10.1021/ja5032369)
• Ambipolar Transport in Phase-Separated Thin Films of p- and n-Type Vanadylporphyrazines with Two-Dimensional Percolation
  • C. Nanjo, T. Fujimoto, M. M. Matsushita, K. Awaga
    J. Phys. Chem. C, 2014, 118(26), 14142-14149 (DOI: 10.1021/jp502056s)
• The key role of vibrational entropy in the phase transitions of dithiazolyl-based bistable magnetic materials
  • S. Vela, F. Mota, M. Deumal, R. Suizu, Y. Shuku, A. Mizuno, K. Awaga, M. Shiga, J. J Novoa, & J. Ribas-Arino
    Nature Communications, 2014, 5, 4411 (DOI:10.1038/ncomms5411)
• Crystal-to-Crystal Transformation in Solid-State Electrochemical Doping of Cl^－ Ions to a Nano-Porous Neutral Radical, Lithium Phthalocyanine; Revelation of Electron-Electron Correlations in a 1D Half-Filled System
  • Y. Miyoshi, H. Yoshikawa, K. Awaga
    CrystEngComm, 2014, 16(39), 9266-9272 (DOI: 10.1039/C4CE01222D)
• Monitoring the Solid-state Electrochemistry of Cu(2,7-AQDC) (AQDC=anthraquinone dicarboxylate) in a Lithium Battery: Coexistence of Metal and Ligand Redox Activities in a Metal-Organic Framework
  • Z. Zhang, H. Yoshikawa, K. Awaga
    J. Am. Chem. Soc., 2014, 136(46), 16112-16115 (DOI: 10.1021/ja508197w)

発表論文 Original Papers 2013

• Synthesis, optical properties and charge transport characteristics of a series of novel thiophene-fused phenazine derivatives
  • Y. Xie, T. Fujimoto, S. Dalgleish, Y. Shuku, M. M. Matsushita, K. Awaga
    J. Mater. Chem. C, 2013, 1, 3467-3481
• Electric-double-layer field-effect transistors with ionic liquids
  • T. Fujimoto, K. Awaga
    Phys. Chem. Chem. Phys., 2013, 15, 8983-9006
• Electronic structure of organic biradical molecular films
  • K. Kanai, H. Koike, R. Suizu, K. Awaga, K. Mase, T. Kubo
    J. Vacuum Soc. Jpn., 2013, 56, 32-38
• In situ Seamless Magnetic Measurements for Solid-State Electrochemical Processes in Prussian Blue Analogues
  • T. Yamada, K. Morita, H. Wang, K. Kume, H. Yoshikawa, K. Awaga
    Angew. Chem. Int. Ed., 2013, 52, 6238-6241
• Capacitance Effects Superimposed on Redox Processes in Molecular-Cluster Batteries: A Synergic Route to High-Capacity Energy Storage
  • H. Wang, Z. Zeng, N. Kawasaki, H. Eckert, H. Yoshikawa, K. Awaga
    Chem. Eur. J., 2013, 19, 11235-11240
• Molecule-displacive ferroelectricity in organic supramolecular solids
  • H. Ye, Y. Zhang, S. Noro, K. Kubo, M. Yoshitake, Z. Liu, H. Cai, D. Fu, H. Yoshikawa, K. Awaga, R. Xiong, T. Nakamura
    Sci. Rep., 2013, 3, 2249
• Multidimensional Network Structures and Versatile Magnetic Properties of Intermolecular Compounds of a Radical-Anion Ligand, [1,2,5]Thiadiazolo[3,4-f][1,10]phenanthroline-1,1-Dioxide
  • Y. Shuku, R. Suizu, A. Domingo, C. J. Calzado, V. Robert, K. Awaga
    Inorg. Chem. 2013, 52, 9921-9930
• Solvent-Induced Assembly of Octacyanometalates-Based Coordination Polymers with Unique cjq Topology and Magnetic Properties
  • J. Qian, J. Hu, J. Zhang, H. Yoshikawa, K. Awaga, C. Zhang
    Crystal Growth & Design, 2013, 13, 5211-5219
• Mn12 single molecule magnets deposited on μ-SQUID sensors the role of interphases and structural modifications
  • E. Bellido, P. Gonzalez-Monje, A. Repolles, M. Jenkins, J. Sese, D. Drung, T. Schurig, K. Awaga, F. Luis, D. Ruiz-Molina
    Nanoscale, 2013, 5, 12565-12573
• Giant Magnetoresistance in a Molecular Thin Film as an Intrinsic Property
  • L. Pilia, M. Serri, M. M. Matsushita, K. Awaga, S. Heutz, N. Robertson
    Adv. Funct. Mater., 2014, 24(16), 2383-2388
• A new metal-organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior
  • Z. Zhang, H. Zhao, M. M. Matsushita, K. Awaga, K. R. Dunbar
    J. Mater. Chem. C, 2014, 2, 399-404
• Transition metal complexes and radical anion salts of 1,10-phenanthroline derivatives annulated with a 1,2,5-tiadiazole and 1,2,5-tiadiazole 1,1-dioxide moiety: multidimensional crystal structures and various magnetic properties
  • Y. Shuku, K. Awaga
    Molecules, 2014, 19(1), 609-640
• Enhanced capacitor effects in polyoxometalate/graphene nanohybrid materials; a synergetic approach to high performance energy storages
  • K. Kume, N. Kawasaki, H. Wang, T. Yamada, H. Yoshikawa, K. Awaga
    J. Mater. Chem. A, 2014, 2(11), 3801-3807
• Thiadiazole Dioxide-Fused Picene: Acceptor Ability, Anion Radical Formation, and n-Type Charge Transport Characteristics
  • Y. Xie, Y. Shuku, M. M. Matsushita, K. Awaga
    Chem. Commun. 2014, 50(32), 4178-4180
• Electron-Transfer Processes in Highly-Correlated Electron Systems of Thiazyl Radicals
  • K. Awaga, K. Nomura, H. Kishida, W. Fujita, H. Yoshikawa, M. M. Matsushita, L. Hu, Y. Shuku, and R. Suizu
    Bull. Chem. Soc. Jpn., 2014, 87(2), 234-249
• Storage of an electric field for photocurrent generation in ferroelectric-functionalized organic devices
  • L. Hu, S. Dalgleish, M. M. Matsushita, H. Yoshikawa, and K. Awaga
    Nat. Commun., 2014, 5, 4279/1-4279/8
• An Antiaromatic Electrode-Active Material Enabling High Capacity and Stable Performance of Rechargeable Batteries
  • J-Y. Shin, T. Yamada, H. Yoshikawa, K. Awaga, H. Shinokubo
    Angew. Chem. Int. Ed., 2014, 53(12), 3096-3101
• Third-Order Nonlinear Optical Properties and Electroabsorption Spectra of an Organic Biradical, [Naphtho[2,1-d:6,5-d']bis([1,2,3]dithiazole)]
  • K. Takauji, R. Suizu, K. Awaga, H. Kishida, A. Nakamura
    J. Phys. Chem. C, 2014, 118(8), 4303-4308

発表論文 Original Papers 2012

• Molecular cluster batteries of nano-hybrid materials between Keggin POMs and SWNTs
  • H. Wang, N. Kawasaki, T. Yokoyama, H. Yoshikawa, K. Awaga
    Dalton Trans., 2012, 41, 9863-9866
• Highly efficient organic optoelectronic conversion induced by electric double layers in ionic liquids
  • B. Li, Y. Noda, L. Hu, H. Yoshikawa, M. M. Matsushita, K. Awaga
    Appl. Phys. Lett., 2012, 100, 163304/1-163304/4
• Electric double layers allow for opaque electrodes in high performance organic optoelectronic devices
  • B. Li, S. Dalgleish, Y. Miyoshi, H. Yoshikawa, M. M. Matsushita, K. Awaga
    App. Phys. Lett., 2012, 101, 173302/1-173302/5
• Utilizing Photocurrent Transients for Dithiolene-Based Photodetection: Stepwise Improvements at Communications Relevant Wavelengths
  • S. Dalgleish, M. M. Matsushita, L. Hu, B. Li, H. Yoshikawa, K. Awaga
    J. Am. Chem. Soc., 2012, 134, 12742-12750
• Planar Ni(II), Cu(II) and Co(II) tetraaza[14]annulenes. Structural, electronic and magnetic properties and application to field effect transistors
  • A. M. Whyte, Y. Shuku, G. Nichol, M. M. Matsushita, K. Awaga, and N. Robertson
    J. Mater. Chem., 2012, 22, 17967-17975
• Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III)
  • H.-L. Cai, Y. Zhang, D.-W. Fu, W. Zhang, T. Liu, H. Yoshikawa, K. Awaga, R.-G. Xiong
    J. Am. Chem. Soc., 2012, 134, 18487-18490
• Ambipolar Carrier Injections Governed by Electrochemical Potentials of Ionic Liquids in Electric-Double-Layer Thin-Film Transistors of Lead- and Titanyl-Phthalocyanine
  • T. Fujimoto, M. M. Matsushita, K. Awaga
    J. Phys. Chem. C, 2013, 117, 5552-5557

発表論文 Original Papers 2011

• 4-cyanomethylanilinium perchlorate. A new displacive-type molecular ferroelectric
  • H.-L. Cai, W. Zhang, J.-Z. Ge, Y. Zhang, K. Awaga, T. Nakamura and R.-G. Xiong
    Phys. Rev. Lett., 2011, 107, 147601/1-147601/5
• A complementary organic inverter of porphyrazine thin films: low-voltage operation using ionic liquid gate dielectrics
  • T. Fujimoto, Y. Miyoshi, M. M. Matsushita and K. Awaga
    Chem. Commun., 2011, 47, 5837-5839
• Solid state NMR strategies for the structural characterization of new hybrid materials based on the intercalation of nitroxide radicals into CdPS3
  • W. L. Hemme, W. Fujita, K. Awaga, H. Eckert
    Solid State Nucl. Mag. Res., 2011, 39, 106-115
• Effect of photoinduced charge displacement on organic optoelectronic conversion
  • L. Hu, A. Iwasaki, R. Suizu, Y. Noda, B. Li, H. Yoshikawa, M. M. Matsushita, K. Awaga, H. Ito
    Phys. Rev. B, 2011, 84, 205329/1-205329/5
• A complementary organic inverter of porphyrazine thin films: low-voltage operation using ionic liquid gate dielectrics
  • T. Fujimoto, Y. Miyoshi, M. M. Matsushita, K. Awaga
    Chem. Commun., 2011, 47, 5837-5839
• Monovalent and Mixed-Valent Potassium Salts of [1,2,5]Thiadiazolo[3,4-f][1,10]phenanthroline 1,1-Dioxide: A Radical Anion for Multidimensional Network Structures
  • Y. Shuku, R. Suizu, K. Awaga
    Inorg. Chem., 2011, 50, 11859-11861
• Structural, Magnetic, and Electronic Properties of Phenolic Oxime Complexes of Cu and Ni
  • A. M. Whyte, B. Roach, D. K. Henderson, P. A. Tasker, M. M. Matsushita, K. Awaga, F. J. White, P. Richardson, N. Robertson
    Inorg. Chem., 2011, 50, 12867-12876
• Formation of stable neutral copper bis-dithiolene thin films by potentiostatic electrodeposition
  • S. Dalgleish, K. Awaga, N. Robertson
    Chem. Commun., 2011, 47, 7089-7091
• In Operando X-ray Absorption Fine Structure Studies of Polyoxometalate Molecular Cluster Batteries: Polyoxometalates as Electron Sponges
  • H. Wang, S. Hamanaka, Y. Nishimoto, S. Irle, T. Yokoyama, H. Yoshikawa, K. Awaga
    J. Am. Chem. Soc., 2012, 134, 4918-4924
• Crystal Structure, Spin Polarization, Solid-State Electrochemistry, and High n-Type Carrier Mobility of a Paramagnetic Semiconductor: Vanadyl Tetrakis(thiadiazole)porphyrazine
  • Y. Miyoshi, K. Takahashi, T. Fujimoto, H. Yoshikawa, M. M. Matsushita, Y. Ouchi, M. Kepenekian, V. Robert, M. P. Donzello, C. Ercolani, K. Awaga
    Inorg. Chem., 2012, 51, 456-462
• Ionic-Liquid Component Dependence of Carrier Injection and Mobility for Electric-Double-Layer Organic Thin-Film Transistors
  • T. Fujimoto, M. M. Matsushita, K. Awaga
    J. Phys. Chem. C, 2012, 116, 5240-5245

発表論文 Original Papers 2010

• Dual-gate field-effect transistors of octathio[8]circulene thin-films with ionic liquid and SiO2 gate dielectrics
  • T. Fujimoto, M. M. Matsushita, K. Awaga
    Appl. Phys. Lett., 2010, 97, 123303/1-123303/3
• Tetrakis(thiadiazole)porphyrazines. 7. Synthesis and structure of mu-oxo-bis[tetrakis(thiadiazole)porphyrazinato-aluminum(III)]
  • M. P. Donzello, M. Fujimori, Y. Miyoshi, H. Yoshikawa, E. Viola, K. Awaga, C. Ercolani
    J. Por. Phtha., 2010, 14, 343-348
• A Novel Free Radical Probe Based on a Preluminescent Iridium Complex Bearing a Nitronyl Radical Moiety
  • H. Yoshikawa, M. Kobayashi, T. Takahashi, and K. Awaga
    Bull. Chem. Soc. Jpn., 2010, 83, 762-766
• Intermolecular band dispersion in a self-assembled phthalocyanine derivative film: The case of tetrakis(thiadiazole)porhyrazine
  • Y. Tanaka, K. Takahashi, T. Kuzumaki, Y. Yamamoto, K. Hotta, A. Harasawa, Y. Miyoshi, H. Yoshikawa, Y. Ouchi, N. Ueno, K. Seki, K. Awaga, and K. Sakamoto
    Phys. Rev. B, 2010, 82, 073408/1-4
• Optoelectronic conversion by polarization current, triggered by space charges at organic-based interfaces
  • L. Hu, Y. Noda, H. Ito, H. Kishida, A. Nakamura, K. Awaga
    Appl. Phys. Lett., 2010, 96, 243303
• Exceptional Dielectric Phase Transitions in a Perovskite-Type Cage Compound
  • W. Zhang, Y. Cai, R.-G. Xiong, H. Yoshikawa, K. Awaga
    Angew. Chem. Int. Ed., 2010, 49, 6608-6610
• In-situ XAFS Studies of Mn12 Molecular-Cluster Batteries: Super-Reduced Mn12 Clusters in Solid-State Electrochemistry
  • H. Wang, S. Hamanaka, T. Yokoyama, H. Yoshikawa, K. Awaga
    Chem. Asian J., 2011, 6, 1074-1079
• Nanohybridization of Polyoxometalate Clusters and Single-Wall Carbon Nanotubes: Applications in Molecular Cluster Batteries
  • N. Kawasaki, H. Wang, R. Nakanishi, S. Hamanaka, R. Kitaura, H. Shinohara, T. Yokoyama, H. Yoshikawa, K. Awaga
    Angew. Chem Int. Ed., 2011, 50, 3471-3474
• Two 3D Coordination Assemblies with Same Cluster Configuration Showing Different Magnetic Behaviors: A Ferromagnetic {[W(CN)8Co2(DMF)8][NO3]}n and A Paramagnetic {W(CN)8Cu2(py)8}
  • J. Qian, H. Zhao, H. Wei, J. Li, J. Zhang, H. Yoshikawa, K. Awaga, C. Zhang
    CrystEngComm., 2011, 13, 517-523
• Electrodeposition as a superior route to a thin film molecular semiconductor
  • S. Dalgleish, H. Yoshikawa, M. M. Matsushita, K. Awaga, N. Robertson
    Chem. Sci., 2011, 2, 316-320
• Photoconductivity and FET Performance of an n-Type Porphyrazine Semiconductor, Tetrakis(thiadiazole)porphyrazin
  • Y. Miyoshi, T. Fujimoto, H. Yoshikawa, M. M. Matsushita, K. Awaga, T. Yamada, H. Ito
    Organic Electronics, 2011, 12, 239-243